Abstract
This paper reports on our study of the mixedligand βiminoketonate complex [PtCl(ktf)H2O] including 1,1,1-trifluoro-4-imino-2-pentanone as a ligand. An X-ray diffraction analysis was performed on a CAD-4 diffractometer (MoKα radiation, ω/2θ scan mode). Crystal data ofPtClF3O2NC5H7: a = 26.264(5), b = 4.750(1), c = 15.955(3) A, β = 108.16(3)°, V = 1891.3A3, space group C2/c, Z = 8, dcalc = 2.82 g/cm3. The Pt atom has a distorted square planar environment. The Pt-Cl, Pt-O(H2O), Pt-N, and Pt-O bonds are 2.29, 2.07, 1.97, and 1.98 A in length, respectively. The chelate angle is 93.7°. The environment of Pt is completed to pyramidal due to interactions with the Cγ atom of the neighboring molecule at a distance of 3.57 A. The compound has a molecular structure. The molecules of the complex are stacked along the Y direction.
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