Abstract
[{MoBr2(O){OPH(OPr i )2}2}2(μ-O)] (1) crystallizes in the monoclinic space group P21/n, with a = 13.063(17) A, b = 11.818(14) A, c = 15.889(17) A, β = 90.30(1)°, Z = 2. The dimeric structure contains a bridging oxygen atom at a crystallographic center of symmetry. Each octahedral molybdenum center has trans-bromide ligands, and two cis-OPH(OPr i )2 units, with a terminal oxygen atom trans to one of the OPH(OPr i )2 units.
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