Abstract
A new compound [MNII(Phen)3]2+(B6H7) 2 − is synthesized; its crystal structure is studied by XRD at 100 K. Crystallographic data: C36H38B12N6Mn, M = 739.39, triclinic symmetry, space group P $$ \bar 1 $$ , unit cell parameters: a = 10.3131(3) A, b = 13.4839(4) A, c = 15.1132(4) A; α = 97.696(1)°, β = 108.324(1)°, γ = 102.211(1)°; V = 1903.9(1) A3, Z = 2, d calc = 1.290 g/cm3. The structure is solved by direct and Fourier methods and refined by full-matrix LSM in the anisotropic (isotropic for hydrogen atoms) approximation to the final factor R 1 = 0.036 for 10169 I hkl ≥ 2σ I (Bruker-Nonius X8 APEX CCD diffractometer, λMoK α). The structure contains two crystallographically different anions.
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