Abstract
The asymmetric unit of the title compound, [Fe(C5H5)(C7H8NO2)], contains two independent molecules consisting of a ferrocenyl moiety and a nitrogen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each independent molecule, the cyclopentadienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42 (15) and 0.49 (13)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds into chains along the a-axis direction.
Highlights
The asymmetric unit of the title compound, [Fe(C5H5)(C7H8NO2)], contains two independent molecules consisting of a ferrocenyl moiety and a nitrogen-bound methyl carbamate
126.3 126.3 108.53 (17) 69.62 (11) 70.10 (10) 125.7 125.7 125.7 108.03 (18) 69.75 (11) 69.82 (10) 126.0 126.0 126.0 107.58 (17) 70.18 (9) 69.38 (10) 126.2 126.2 126.2 107.5 (2) 69.84 (12) 69.65 (12) 126.2 126.2 126.2 107.9 (2) 69.86 (11) 69.90 (12) 126.1 126.1 126.1 107.9 (2) 69.95 (12) 69.53 (12) 126.1 126.1 126.1 108.2 (2) 69.85 (12) 69.92 (12) 125.9 125.9 125.9 108.5 (2) 70.04 (12) 69.82 (12) 125.7 sup-7
Summary
Data collection: APEX2 (Bruker, 2014); cell refinement: SAINT (Bruker, 2013); data reduction: SAINT; program(s) used to solve structure: SHELXT-2014 (Sheldrick, 2015); program(s) used to refine structure: SHELXL2014/6 (Sheldrick, 2008); molecular graphics: Mercury (Macrae et al, 2006); software used to prepare material for publication: publCIF (Westrip, 2010)
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