Abstract
Crystal formation of caesium thallium chloride phospho-tungstates, Cs9(TlCl6)(PW12O40)2·9CsCl showcases the ability to capture and crystallize octa-hedral complexes via the use of polyoxometalates (POMs). The large number of caesium chlorides allows for the POM [α-PW12O40]3- to arrange itself in a cubic close-packing lattice extended framework, in which the voids created enable the capture of the [TlCl6]3- complex.
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