Abstract
In the title compound, C35H27N3O3S, the spiro-linked five-membered rings both adopt twisted conformations. The pyrrolidine ring makes dihedral angles of 80.5 (1) and 77.4 (9)° with the benzothiophene ring system and the quinoxaline ring system, respectively. The S atom and C=O unit of the benzothiophene ring system are disordered over two opposite orientations in a 0.768 (4):0.232 (4) ratio. The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio. In the crystal, molecules are linked by C—H⋯O, C—H⋯N and π–π interactions [shortest centroid–centroid distance = 3.4145 (19) Å], resulting in a three-dimensional network.
Highlights
In the title compound, C35H27N3O3S, the spiro-linked fivemembered rings both adopt twisted conformations
The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio
H atoms treated by a mixture of independent and constrained refinement max = 0.21 e Å3
Summary
C35H27N3O3S, the spiro-linked fivemembered rings both adopt twisted conformations. The pyrrolidine ring makes dihedral angles of 80.5 (1) and The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio. H atoms treated by a mixture of independent and constrained refinement max = 0.21 e Å3
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More From: Acta Crystallographica Section E Crystallographic Communications
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