Abstract

In the title compound, C35H27N3O3S, the spiro-linked five-membered rings both adopt twisted conformations. The pyrrolidine ring makes dihedral angles of 80.5 (1) and 77.4 (9)° with the benzo­thio­phene ring system and the quinoxaline ring system, respectively. The S atom and C=O unit of the benzo­thio­phene ring system are disordered over two opposite orientations in a 0.768 (4):0.232 (4) ratio. The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio. In the crystal, mol­ecules are linked by C—H⋯O, C—H⋯N and π–π inter­actions [shortest centroid–centroid distance = 3.4145 (19) Å], resulting in a three-dimensional network.

Highlights

  • In the title compound, C35H27N3O3S, the spiro-linked fivemembered rings both adopt twisted conformations

  • The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio

  • H atoms treated by a mixture of independent and constrained refinement max = 0.21 e Å3

Read more

Summary

Introduction

C35H27N3O3S, the spiro-linked fivemembered rings both adopt twisted conformations. The pyrrolidine ring makes dihedral angles of 80.5 (1) and The atoms of the ethyl side chain are disordered over two sets of sites in a 0.680 (16):0.320 (16) ratio. H atoms treated by a mixture of independent and constrained refinement max = 0.21 e Å3

Results
Conclusion

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.