Abstract
The title compound, C17H24N2O3S, was synthesized in order to determine the relative configuration of the corresponding β-keto aldehyde. In the U-shaped molecule, the five-membered ring approximates an envelope with the methylene atom adjacent to the quaternary C atom being the flap. The dihedral angles between the four nearly coplanar atoms of the five-membered ring and the flap and the aromatic ring are 38.8 (4) and 22.9 (2)°, respectively. The bond angles around the S atom are in the range 104.11 (16)–119.95 (16)°. In the crystal, molecules are linked via N—H⋯O by hydrogen bonds, forming a chain along the a-axis direction.
Highlights
The title compound, C17H24N2O3S, was synthesized in order to determine the relative configuration of the corresponding -keto aldehyde
In the U-shaped molecule, the fivemembered ring approximates an envelope with the methylene atom adjacent to the quaternary C atom being the flap
The bond angles around the S atom are in the range 104.11 (16)–119.95 (16)
Summary
The title compound, C17H24N2O3S, was synthesized in order to determine the relative configuration of the corresponding -keto aldehyde. Fakultat fur Chemie und Chemische Biologie, Technische Universitat Dortmund, Otto-Hahn-Strasse 6, 44221 Received 25 November 2014; accepted 5 December 2014
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