Abstract

The title compound, C17H18O5, was synthesized by a base-free catalytic Wittig reaction. The mol­ecule consists of a diethyl itaconate unit, which is connected via the C=C double bond to a benzo­furan moiety. The benzo­furan ring system (r.m.s. deviation = 0.007 Å) forms dihedral angles of 79.58 (4) and 12.12 (10)° with the mean planes through the cis and trans eth­oxy­carbonyl groups, respectively. An intra­molecular C—H⋯O hydrogen bond involving the O atom of the benzo­furan moiety is observed. In the crystal, mol­ecules are linked into ribbons running parallel to the b axis by C—H⋯O hydrogen bonds.

Highlights

  • The title compound, C17H18O5, was synthesized by a base-free catalytic Wittig reaction

  • The molecule consists of a diethyl itaconate unit, which is connected via the C C double bond to a benzofuran moiety

  • An intramolecular C— HÁ Á ÁO hydrogen bond involving the O atom of the benzofuran moiety is observed

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Summary

Introduction

The title compound, C17H18O5, was synthesized by a base-free catalytic Wittig reaction. V. an der Universitat Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany. Received 6 October 2015; accepted 12 October 2015 The molecule consists of a diethyl itaconate unit, which is connected via the C C double bond to a benzofuran moiety.

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Conclusion

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