Abstract

The crystal structures of dehydrated Li-exchanged A-type zeolites, determined by neutron and X-ray diffraction powder methods, indicate that the majority of the Li-cations are located at the six-ring centres. The framework distortion is progressive from d-K-A to d-Na-A and d-Li-A and follows the charge to radius ratio of the exchangeable cations. The shape of the framework eight-rings changes accordingly.

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