Abstract
The title compound (systematic name: 1-{[2-(cyclopropylcarbonyl)anilino]sulfonyl}-3-(4,6-dimethoxypyrimidin-2-yl)urea), C17H19N5O6S, is a pyrimidinylsulfonylurea herbicide. The dihedral angles between the mean planes of the central benzene ring and the cyclopropyl and pyrimidinyl rings are 75.32 (9) and 88.79 (4)°, respectively. The C atoms of the methoxy groups lie almost in the plane of the pyrimidine ring [deviations = 0.043 (2) and 0.028 (2) Å] and intramolecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds all close S(6) rings. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak π–π interactions [centroid–centroid distances = 3.6175 (9) and 3.7068 (9) Å] link adjacent molecules, forming a three-dimensional network.
Highlights
The dihedral angles between the mean planes of the central benzene ring and the cyclopropyl and pyrimidinyl rings are
In the title compound (Fig. 1), the dihedral angles between the mean planes of the central phenyl ring and the cyclopropyl and pyrimidinyl rings are 75.32 (9) and 88.79 (4)°, respectively
All bond lengths and bond angles are normal and comparable to those observed in a similar crystal structure (Xia et al, 2008)
Summary
The dihedral angles between the mean planes of the central benzene ring and the cyclopropyl and pyrimidinyl rings are. Absorption correction: multi-scan (SADABS; Bruker, 2013) The title compound (systematic name: 1-{[2-(cyclopropylcarbonyl)anilino]sulfonyl}-3-(4,6-dimethoxypyrimidin-2-yl)urea), C17H19N5O6S, is a pyrimidinylsulfonylurea herbicide. The C atoms of the methoxy groups lie almost in the plane of the pyrimidine ring N—H N, N—H O and C—H O hydrogen bonds all close S(6) rings.
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More From: Acta crystallographica. Section E, Crystallographic communications
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