Abstract
At room temperature, the reaction of 2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene-]-4,5-bis(2-cyanoethylsulfanyl)-1, 3-dithiole (CM-TTF) with mercury chloride resulted in a black radical salt constructed by dimeric cations and chloromercurate anions in formula (CM-TTF)2Hg2Cl6. The S···S stacking of 3.289(3) and 3.334(3) A within the TTF dimer are very strong in comparing with those of other TTF radical salts. Effective C···C stacking (3.349(10) A) was also found within the dimeric structure.
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