Abstract
In the title complex, {[Ag(C13H13N5)]NO3}n, the AgI atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C—H⋯O hydrogen bonds link the ions into a three-dimensional network.
Highlights
In the title complex, {[Ag(C13H13N5)]NO3}n, the AgI atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal
The complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counteranions situated in between
Weak C—H O hydrogen bonds link the ions into a three-dimensional network
Summary
In the title complex, {[Ag(C13H13N5)]NO3}n, the AgI atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal–. Received 6 February 2015; accepted 26 February 2015 Planar geometry [range of angles: 83.34 (6) (chelate ring) to
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