Abstract
The title complex, [(PPh3)2Ag(μ-N3)2Ag(PPh3)2], has been synthesized and structurally characterized by single-crystal X-ray diffraction. The silver atoms are joined through a double μ1,3-azido (N3) bridge. To each silver atom are also coordinated two P atoms from two triphenylphosphine molecules. The coordinated polyhedron around silver is a distorted tetrahedron.
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