Abstract
The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent molecules in the asymmetric unit. Each CuII atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligands. In the crystal, the two molecules are linked via weak C—H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.
Highlights
Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université
Their formula mass and unit-cell characteristics were not taken into account during refinement
We report the synthesis and crystal structure of a novel copper(II) complex formed on reaction of a similar azoic ligand, (E)-1-((2-methoxyphenyl)diazenyl)naphthalen-2-ol (C17H14N2O2), with Cu(OAc)2·H2O
Summary
The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent molecules in the asymmetric unit. Each CuII atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate. The two molecules are linked via weak. C—H O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Their formula mass and unit-cell characteristics were not taken into account during refinement
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
