Abstract
The title compound, Ph3(PhCH2)P+·Cl−·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenylphosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. In the crystal, the chloride ion is linked to the water molecule by an O—H⋯Cl hydrogen bond. The three units are further linked via C—H⋯Cl and C—H⋯O hydrogen bonds and C—H⋯ π interactions, forming a three-dimensional structure.
Highlights
The title compound, Ph3(PhCH2)P+ClH2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenylphosphonium as the counter-ion
The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization
The chloride ion is linked to the water molecule by an O—H Cl hydrogen bond
Summary
The title compound, Ph3(PhCH2)P+ClH2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenylphosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. The chloride ion is linked to the water molecule by an O—H Cl hydrogen bond. H O hydrogen bonds and C—H interactions, forming a three-dimensional structure.
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