Abstract
NaSn(OH)(edta)(H2O) is monoclinic, space groupP21/c, witha=9.747(3)A,b=9.121(3)A,c=16.430(6)A, β=98.69(4)°, A3, andZ=4. The coordination environment of Sn(IV) is a capped octahedron. Sn−O distances range from 1.990(6)A to 2.351(7)A. Na(I) is five coordinated to three different edta molecules. Na−O distances range from 2.283(9)A to 2.414(7)A. The edta ligand presents the E, G/R conformation. The crystal structure is composed of sheets parallel to (001): inside a sheet Sn(OH)(edta) molecules are connected to each other by the Na(I) interactions.
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