Abstract
AbstractCesium gallium hydrogen triphosphate CsGaHP3O10‐III crystallizes in the space group Pca21, a = 1 176.3(1) pm, b = 496.55(5) pm, c = 1 572.2(1) pm and Z = 4.The structure was solved by using 1 268 unique reflections Io > 2σ(Io) with a final wR2 value of 0.0742 (SHELXL‐93).The P3O10 chain anions, bonded by Ga, are spreaded in layers parallel (0 0 1); the layers are interconnected by Cspolyhedra and obviously by hydrogen bonds. The interlayer distance is c/2.The new structure is compared with the previously known structures of CsGaHP3O10‐I and Cs3Ga3P12O36.Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), and the Charge Distribution (CHARDI) are calculated for the title compound.
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