Abstract

The crystal structure of a new monoclinic metastable phase of anthracene formed during vapor growth has been determined from single crystal X-ray data (DARCH-1 automatic diffractometer, Mo K α radiation). This metastable anthracene phase crystallizes in the monoclinic space group P2 1 /n with a =8.553(2), b =6.021(1), c =22.334(4), Å and β=124.54(3)°, and four molecules per unit cell. All carbon and hydrogen atom positions have been determined and refined to R=0.044 for 330 unique reflections.

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