Abstract
X-Ray diffraction analysis of a hydrated N-glycoprotein linkage region model, N 1-(2-acetamido-2-deoxy- β- d-glucopyranosyl)acetamide ( 1) and its N 1-benzamido analogue 2 reveals very interesting molecular architecture involving seven hydrogen bonds in both compounds and further stabilization of packing in 2 due to π– π stacking. The crystal structure has a two dimensional network of hydrogen bonds formed by infinite chains running along the b-axis and homodromic cycles, intersecting at the water oxygens.
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