Abstract
A pair of dinucleating ligands, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-methylphenolate (bomp-), incorporates two sodium ions to form a dinuclear sodium complex, [Na2(bomp)2] (C42H74N4Na2O10). It crystallizes in the monoclinic space group P21/c with dimensions a = 19.9993(4)Å, b = 9.9700(2)Å, c = 24.3473(7)Å, β = 98.8492(7)°, and V = 4796.89(19)Å3 and with Z = 4. The two sodium ions are bridged by two phenoxo oxygen atoms of the bomp ligands to form a bis(μ-phenoxo)-dinuclear sodium(I) core structure. The Na…Na distance is 3.3261(6)Å, and each sodium ion has a distorted octahedral geometry.
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