Crystal structure of 4-phenyl-1-{2-[(2,4,6-tri-methyl-phen-yl)selan-yl]phen-yl}-1H-1,2,3-triazole.

Leandro R S Camargo,Julio Zukerman-Schpector,Antonio L Braga,Anna M Deobald,Edward R T Tiekink

doi:10.1107/s2056989015003229

Abstract

In the title compound, C23H21N3Se, the C-bound phenyl ring is almost coplanar with the central five-membered ring [dihedral angle = 2.84 (10)°], but the N-bound benzene ring is inclined [dihedral angle = 47.52 (10)°]. The dihedral angle between the Se-bound rings is 69.24 (9)°. An intramolecular Se⋯N interaction of 3.0248 (15) Å is noted. In the crystal, C—H⋯π interactions connect molecules into double layers that stack along the a axis with no directional interactions between them.

Highlights

In the title compound, C23H21N3Se, the C-bound phenyl ring is almost coplanar with the central five-membered ring [dihedral angle = 2.84 (10) ], but the N-bound benzene ring is inclined [dihedral angle = 47.52 (10) ]
H interactions connect molecules into double layers that stack along the a axis with no directional interactions between them
Supporting information for this paper is available from the IUCr electronic archives (Reference: HG5433)

Summary

Introduction

SP, Brazil, bDepartmento de Quımica, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS, Brazil, cDepartmento de Quımica, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil, and dDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia. C23H21N3Se, the C-bound phenyl ring is almost coplanar with the central five-membered ring [dihedral angle = 2.84 (10) ], but the N-bound benzene ring is inclined Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2011) H-atom parameters constrained max = 0.38 e Å3

Results

Conclusion