Abstract
In the title compound, C17H11Br2N3O4, the dihedral angle between the planes of the naphthalene system and the benzene ring is 52.86 (8)°. The nitro substituent and the attached naphthalene system are almost coplanar [dihedral angle = 5.6 (4)°], probably as a consequence of an intramolecular N—H⋯O hydrogen bond with the amine group. The nitro substituent attached to the benzene ring is disordered over two sets of sites with occupancies of 0.694 (3) and 0.306 (3). The major component deviates significantly from the ring plane [dihedral angle = 53.6 (2)°]. In the crystal, the molecules are linked into a three-dimensional array by extensive π–π interactions involving both the naphthalene and benzene rings [range of centroid–centroid distances = 3.5295 (16)–3.9629 (18) Å] and C—H⋯O interactions involving the methylene H atoms and the phenyl-attached nitro group.
Highlights
For the isolation of novel photoluminescent selenospirocyclic compounds via intermolecular C—C bond formation, see: Singh et al (2011)
The nitro substituent attached to the benzene ring is disordered over two sets of sites with occupancies of
The molecules are linked into a threedimensional array by extensive – interactions involving both the naphthalene and benzene rings [range of centroid
Summary
For the role of secondary interactions in stabilizing organoselenium compounds, see; Singh et al (2010, 2012); Mugesh &. For the isolation of novel photoluminescent selenospirocyclic compounds via intermolecular C—C bond formation, see: Singh et al (2011)
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More From: Acta crystallographica. Section E, Structure reports online
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