Abstract
In the title solvate, C15H15N3O2S·CH3OH, the thiosemicarbazone molecule is approximately planar; the maximum deviation from the mean plane is 0.4659 (14) Å and the dihedral angle between the aromatic rings is 9.83 (8)°. This conformation is supported by an intramolecular N—H⋯N hydrogen bond. In the crystal, the thiosemicarbazone molecules are linked into dimers by pairs of N—H⋯S hydrogen bonds, thereby generating R 2 2(8) loops. The methanol solvent molecule bonds to the thiosemicarbazone molecule through a bifurcated O—H⋯(O,O) hydrogen bond and also accepts an O—H⋯O link from the thiosemicarbazone molecule. Together, these links generate a three-dimensional network.
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