Abstract
The molecular geometry of the ionic title compound, C14H17N4 +·I− or DAZOP+·I−, is essentially featureless. Regarding the crystal structure, in addition to the obvious cation–anion Coulombic interactions, the packing is mostly directed by non-covalent interactions involving both ring systems, as well as the iodide anion. It consists of cationic molecules aligned along [101] and disposed in an antiparallel fashion while linked into π-bonded dimeric entities by a stacking contact involving symmetry-related phenyl rings, with a centroid–centroid distance of 3.468 (3) Å and a slippage of 0.951 Å. The dimers are, in addition, sustained by a number of C—H⋯I and I⋯π (I⋯centroid = 3.876 Å) interactions involving the anion. Finally, interdimeric contacts are of the C—H⋯I and C—H⋯π types.
Highlights
The molecular geometry of the ionic title compound, C14H17N4+ÁIÀ or DAZOP+ÁIÀ, is essentially featureless
In addition to the obvious cation–anion Coulombic interactions, the packing is mostly directed by non-covalent interactions involving both ring systems, as well as the iodide anion
It consists of cationic molecules aligned along [101] and disposed in an antiparallel fashion while linked into -bonded dimeric entities by a stacking contact involving symmetry-related phenyl rings, with a centroid–centroid distance of 3.468 (3) Aand a slippage of 0.951 A
Summary
The molecular geometry of the ionic title compound, C14H17N4+ÁIÀ or DAZOP+ÁIÀ, is essentially featureless. Universitat de Valencia, Instituto de Reconocimiento Molecular y Desarrollo Tecnologico, Doctor Moliner 50,46100, Burjassot,Valencia, Spain. In addition to the obvious cation–anion Coulombic interactions, the packing is mostly directed by non-covalent interactions involving both ring systems, as well as the iodide anion. It consists of cationic molecules aligned along [101] and disposed in an antiparallel fashion while linked into -bonded dimeric entities by a stacking contact involving symmetry-related phenyl rings, with a centroid–centroid distance of 3.468 (3) Aand a slippage of 0.951 A .
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