Abstract
In the title compound, C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C=N bonds is E and the substituted biphenyl units are trans to one another. In the two biphenyl ring systems, the planes of the two rings are inclined to one another by 25.25 (19) and 28.01 (19)°. The planes of the ethyl-substituted benzene rings are inclined to one another by 20.23 (19)° and to the mean plane of the butane-2,3-diimine unit [maximum deviation = 0.014 (4) Å] by 83.19 (19) and 63.38 (19)°. In the crystal, molecules are linked by C—H⋯π interactions, forming sheets lying parallel to (101).
Highlights
In the title compound, C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C N bonds is E and the substituted biphenyl units are trans to one another
Molecules are linked by C—HÁ Á Á interactions, forming sheets lying parallel to (101)
Cg2 and Cg4 are the centroids of rings C7-C12 and C23-C28, respectively
Summary
C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C N bonds is E and the substituted biphenyl units are trans to one another. Received 6 March 2015; accepted 12 March 2015 In the two biphenyl ring systems, the planes of the two rings are inclined to one another by 25.25 (19) and 28.01 (19).
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