Abstract
The tin(IV) atom in the complex anion of the title salt, (C4H7N2)[Sn(C2O4)Cl3(H2O)], is in a distorted octa-hedral coordination environment defined by three chlorido ligands, an oxygen atom from a water mol-ecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N-H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H2O)Cl3(C2O4)](-) anion. Neighbouring stannate(IV) anions are linked through O-H⋯O hydrogen bonds involving the water mol-ecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N-H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned.
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More From: Acta crystallographica. Section E, Crystallographic communications
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