Abstract

The asymmetric unit of the title salt, C7H7N2 +·ClO4 −, comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra­molecular layers are stabilized and connected by C—H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin­ium–perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

Highlights

  • The asymmetric unit of the title salt, C7H7N2+ClO4, comprises two independent formula units

  • The crystal was refined as an inversion twin

  • Supporting information for this paper is available from the IUCr electronic archives (Reference: TK5395)

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Summary

Introduction

The asymmetric unit of the title salt, C7H7N2+ClO4, comprises two independent formula units. Koplitza a Department of Chemistry, Loyola University, New Orleans, LA 70118, USA, and Department of Chemistry, Tulane University, New Orleans, LA 70118, USA. Received 9 October 2015; accepted 10 October 2015 Monoclinic, P21 a = 8.0112 (12) Å

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