Abstract
The title molecule, C16H9BrO3, deviates slightly from planarity. The benzene ring makes a dihedral angle of 1.02 (9)° with the plane defined by the five-membered ring of the indandione moiety. The latter exhibits a minute twist indicated by the dihedral angle of 0.47 (9)° between the planes of the five- and six-membered rings. An intramolecular C—H⋯O hydrogen bond between the attached benzene ring with one of the indandione carbonyl O atoms stabilizes the molecular conformation. In the crystal, the molecules form dimers across centres of inversion via pairwise O—H⋯O hydrogen bonds. The dimers form stacks running parallel to [010] and interact through π–π interactions between the five-membered ring of one molecule and the six-membered rings of the indandione moiety of an adjacent molecule [centroid-to-centroid distance = 3.5454 (10) Å].
Highlights
The title molecule, C16H9BrO3, deviates slightly from planarity
The benzene ring makes a dihedral angle of 1.02 (9) with the plane defined by the five-membered ring of the indandione moiety
The latter exhibits a minute twist indicated by the dihedral angle of 0.47 (9) between the planes of the five- and six-membered rings
Summary
The title molecule, C16H9BrO3, deviates slightly from planarity. The benzene ring makes a dihedral angle of 1.02 (9) with the plane defined by the five-membered ring of the indandione moiety. ISSN 2056-9890 ities of 3-substituted indan-1,3-diones, see: Hochrainer & Wessely (1966); Zargar & Khan (2015). The title molecule, C16H9BrO3, deviates slightly from planarity.
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More From: Acta crystallographica. Section E, Crystallographic communications
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