Abstract
The structure of the title compound, C27H46N2, at 93 K has monoclinic (P21/n) symmetry. The title compound was prepared by treatment of 2-(2,6-diiso-propyl-phenyl)-3,3-dimethyl-2-aza-spiro-[4.5]dec-1-en-2-ium hydrogen dichloride with two equivalents of lithium di-ethyl-amide. Characterization of the title compound by single-crystal X-ray diffraction and 1H and 13C NMR spectroscopy is presented. Formation of the di-ethyl-amine adduct of the cyclic(alk-yl)(amino)-carbene (CAAC) was unexpected, as deprotonation using lithium diiso-propyl-amide results in free CAAC formation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta crystallographica. Section E, Crystallographic communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
