Abstract
The present crystal structure of 2,12-dichlorocyclododecanone was determined by X-ray analysis. The 12-membered ring has 422-symmetry, containing eight torsion angels having synclinal conformations of approximately 65° (average 68.05°); the other four torsion angels conforming antiperiplanar conformations are the average of 160.7°, respectively. The effects of the carbonyl group and the Cl atoms on the conformation of the ring are also discussed.
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