Abstract
In the title compound, C30H20O2S2, the dihedral angles between the central azulene ring system (r.m.s. deviation = 0.039 Å) and the pendant benzene rings are 28.96 (7) and 55.15 (7)°. The dihedral angles between the benzene rings and their attached acetylsulfanyl groups are 59.60 (10) and 84.79 (10)°. The expected π–π stacking interactions are not observed in the crystal structure; instead, the packing features C—H⋯O hydrogen bonds, which link the molecules into C(12) [010] chains, which are supported by weak C—H⋯π contacts.
Highlights
C30H20O2S2, the dihedral angles between the central azulene ring system (r.m.s. deviation = 0.039 A ) and the pendant benzene rings are 28.96 (7) and 55.15 (7)
The dihedral angles between the benzene rings and their attached acetylsulfanyl groups are 59.60 (10) and 84.79 (10)
The expected – stacking interactions are not observed in the crystal structure; instead, the packing features C—HÁ Á ÁO hydrogen bonds, which link the molecules into C(12) [010] chains, which are supported by weak C—HÁ Á Á contacts
Summary
= 0.25 mmÀ1 T = 100 K 0.24 Â 0.23 Â 0.15 mm Absorption correction: multi-scan (SADABS; Bruker, 2008) Tmin = 0.942, Tmax = 0.963 36340 measured reflections 5898 independent reflections 4422 reflections with I > 2(I) Rint = 0.039
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta crystallographica. Section E, Crystallographic communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
