Crystal structure, magnetic properties and advances in hexaferrites: A brief review

Abstract

Hexaferrites are hard magnetic materials and specifically ferri-magnetic oxides with hexagonal magnetoplumbite type crystallographic structure. Hexagonal ferrites are used as permanent magnets, high-density perpendicular and magneto-optical recording media, and microwave devices like resonance isolators, filters, circulators, phase shifters because of their high magnetic permeability, high electrical resistivity and moderable permittivity. In addition to these; hexagonal ferrites have excellent chemical stability, mechanical hardness and low eddy current loss at high frequencies. The preparation of hexaferrites is a complicated process. Various experimental techniques like standard ceramic techniques, solvent free synthesis route, co precipitation, salt-melt, ion exchange, sol-gel, citrate synthesis, hydrothermal synthesis, spray drying, water-in-oil microemulsion, reverse micelle etc are used to prepare hexaferrite materials. Structural, dielectric and magnetic properties, crystallite size of hexaferrites depend upon nature of substituted ions, method of preparation, sintering temperature and time. The recent interest is nanotechnology, the development of hexaferrite fibres and composites with carbon nano tubes (CNT). Magnetic properties of some doped and un-doped hexaferrites are discussed here. Recent advances in hexaferrites also highlighted in present paper.