Abstract
The crystal structures of the host-guest supramolecular complexes [2(6-HPCH)2+.3(18C6)].4[ClO4¯].2(H2O) (I) and [(PDA)2+.2(18C6)].2[Cl¯].10(H2O) (II) (18C6 = 18-crown-6; 6HPCH = 6-hydrazinylpyridine-1-ium-3-carbohydrazinium; PDA = p-phenylenediaminium) were determined by single-crystal X-ray diffraction analysis. Supramolecular assembly is constructed by NH···O, OH···O and C-H···O interactions. Both crystallize in the monoclinic system with centrosymmetric space group P21/n. The vibrational patterns in FT–IR are used to identify the functional groups. Direct band gap energy estimated by diffuse reflectance spectrum are, 3.42 eV for (I) and 4.78 eV for (II). Molecular interactions are analyzed by Hirshfeld surfaces, derived from single-crystal XRD data. Fingerprint plots of Hirshfeld surfaces were used to locate and analyze the percentage of hydrogen bonding interactions. A z-scan study was used to determine the third-order NLO response.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
