Abstract
We synthesized a new type of asymmetric binuclear Ag(I) complex, [Ag2(dppaO2)2(dppbz)] (1), consisting of two chelating dppaO2− ligands (dppaO2− = N,N-bis(diphenylphosphino)amide-dioxide) and one bridging dppbz ligand (dppbz = 1,2-bis(diphenylphosphino)-benzene). According to X-ray crystal structure analysis, the two Ag(I) ions were adjacent to each other and were bridged by both the dppbz ligands and one of the oxygen atoms in the dppaO2− ligands. Complex 1 showed relatively strong green luminescence in the solid state.
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