Abstract
The compound {o-(Ph2P)C6H4}2Sn(CH3)2 was rigorously purified and examined by single crystal X-ray diffraction (XRD) studies at three different temperatures and by temperature-dependent Mössbauer effect (ME) determination at 8 temperatures in the interval 87<T<245K. The oxidation state of the metal atom is Sn(IV) and the absence of a resolvable quadrupole interaction in the ME data confirms previous results for Sn ligated only to C atoms, despite the obvious absence of Td or Oh symmetry. The vibrational amplitudes inferred from the ME data are compared to the XRD data at three different temperatures and to a related solid.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
