Abstract
AbstractTwo bimetallic magnetic chain compounds of {[Mn(dpop)(H2O)][Mn(dpop)][Fe[CN]6]•8.5H2O•0.5DMSO} n (1) and {[Mn(dpop)][Ni[CN]4]} n (2) (dpop = 2,13‐dimethyl‐3,6,9,12,18‐pentaazabicyclo‐[12.3.1]‐octadeca‐1(18),2,12,14,16‐pentaene) have been synthesized and characterized by single‐crystal X‐ray diffraction and magnetic measurements. Both complexes have cyano‐bridged chain structures, in which complex 1 is a zigzag chain, while complex 2 is nearly a straight line. The magnetic susceptibility results indicate that there is a weak ferromagnetic interaction between manganese (II) ions in complex 1, whereas the interaction is antiferromagnetic in complex 2.
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