Abstract
The compound [Cr(en) 3][ZnCl 4]Cl has been synthesized by reaction of CrCl 3·6H 2O, Zn and [Cr(en) 3] 2(SO 4) 3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P2 1/ c, a=21.215(3), b=12.532(2), c=13.707(2) Å, β=95.21°, V= 3629(2) Å 3, D x=1.738g cm −3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 Å, μ(Mo Kα)= 27.04 cm −1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested ( g 1=2.06±0.02, g 2= 2.08±0.02, g 3=2.09±0.01), T=1.2-1.4 K.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
