Abstract
In the title compound, C25H20O2, the central cyclo-hexenone ring adopts an envelope conformation. The mean plane of the cyclo-hexenone ring makes dihedral angles of 87.66 (11) and 23.76 (12)°, respectively, with the two attached phenyl rings, while it is inclined by 69.55 (11)° to the phenyl ring of the benzoyl group. In the crystal, the mol-ecules are linked by C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional network.
Highlights
In the title compound, C25H20O2, the central cyclohexenone ring adopts an envelope conformation
As part of a further study on the chemistry of, -unsaturated ketones (Naghiyev et al, 2016), we report the crystal structure and Hirshfeld surface analysis of the title compound
Cg2 and Cg3 are the centroids of the C8–C13 and C14–C19 phenyl rings, respectively
Summary
There have been a series of significant examples of enone derivatives used as target products as well as synthetic intermediates (Abdelhamid et al, 2011; Asgarova et al, 2019; Khalilov et al, 2018a,b; Thomas, 2007). A number of useful compounds containing enone moieties have been found in nature, such as cyanthiwigin U, (+)-cepharamine, phorbol and grandisine G, which were the object of a total synthesis (Pfeiffer et al, 2005; Schultz & Wang, 1998; Kawamura et al, 2016; Cuthbertson & Taylor, 2013). As part of a further study on the chemistry of , -unsaturated ketones (Naghiyev et al, 2016), we report the crystal structure and Hirshfeld surface analysis of the title compound
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