Crystal structure and heat capacity of the mixed-valence trinuclear iron monoiodoacetate complex, [Fe(III) 2Fe(II)O(O 2CCH 2I) 6(H 2O) 3][Fe(III) 3O(O 2CCH 2I) 6(H 2O) 3

Abstract

The crystal structure of a trinuclear iron monoiodoacetate complex was determined. Although it has been incorrectly characterized as [Fe 3O(O 2CCH 2I) 6(H 2O) 3], the correct chemical formula turned out to be [Fe(III) 2Fe(II)O(O 2CCH 2I) 6(H 2O) 3]-[Fe(III) 3O(O 2CCH 2I) 6(H 2O) 3]I ( 1). The two kinds of Fe 3O molecules (Fe(III) 2Fe(II)O and Fe(III) 3O) are crystallographically indistinguishable. All the Fe atoms are crystallographically equivalent because of a crystallographic threefold symmetry. Heat capacities of 1 seem to exhibit no thermal anomaly in the temperature range 5.5–309 K, although the valence detrapping phenomenon has been observed in this temperature range. This fact indicates that the valence-detrapping phenomenon in 1 occurs without any phase transition, leading 1 to a glassy state, probably because the crystal of 1 is just like a solid solution of distorted mixed-valence Fe(III) 2Fe(II)O molecules and permanently undistorted Fe(III) 3O molecules which may act as an inhibitor for a cooperative valence-trapping.