Abstract
Zirconium oxides formed on Zirclaoy-4 and Zr–1.5Nb (in wt%) were characterized by the microbeam X-ray diffraction using a synchrotron radiation. The phase fraction and the grain size were determined as a function of the position in the oxide. It was found that Zr–1.5Nb showed the better corrosion resistance than Zircaloy-4 in 360°C pure water although the tetragonal phase was more stabilized to a further distance from the metal/oxide interface in the oxide of Zircaloy-4. The calculation of the grain size revealed that the oxide of the Zr–1.5Nb had larger grains than that of Zircaloy-4 with the tetragonal phase being smaller than the monoclinic one. It seems reasonable to suppose that the superior corrosion resistance of Zr–1.5Nb was attributed to the lager grain size of the oxide in which the oxygen diffusion is expected to be lowered when compared to the smaller grain size of the oxide on Zircaloy-4.
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