Abstract
A new Cu(II) coordination polymer, namely {[Cu2(btb)2(sip)(OH)]•(H2O)0.25}n (btb = 4,4′-bis(1,2,4- triazolyl-1-yl)-biphenyl, H3sip = 5-sulfoisophthalic acid), is hydrothermally synthesized and characterized by elemental analyses, infrared (IR) spectroscopy, and single crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/c, a = 14.9676(3) A, b = 14.3478(3) A, c = 21.2719(5) A, β = 125.325(2)°, V = 3727.11(14) A3, Z = 4, C40H28.50Cu2N12O8.25S, Mr = 968.39, Dc = 1.726 g/cm3, μ = 1.274 mm–1. The structural analyses reveal that the compound displays a 2D binodal rarely (4,5)-connected network with 4,5L50 topology. Moreover, the thermal and catalytic properties of the complex for the degradation of the congo red azo dye in a Fenton-like process are investigated.
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