Abstract
Zeeman effect studies of Cl35 nuclear quadrupole resonance have been carried out at room temperature in a single crystal of 3,5-dichlorophenol. It was confirmed that the crystal belongs to monoclinic symmetry. Two inequivalent field gradient systems were observed. The asymmetry parameter of the field gradient was found to be 0.09± 0.03. The minimum number of molecules in the unit cell and the orientation of the molecular planes with respect to the C axis of the crystal, which is also the growth axis, have been determined. The bond characters of the C–Cl bond have been calculated using the experimental asymmetry parameter.
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