Abstract
Lithium phosphate (Li3PO4) is one of the promising solid electrolyte materials for lithium-ion battery because of its high ionic conductivity. A crystalline form of Li3PO4 had been prepared by two different methods. The first method was wet chemical reaction between LiOH and H3PO4, and the second method was solid-state reaction between Li2O and P2O5. Crystal structure of Li3PO4 white powder had been investigated by using an X-ray diffraction (XRD) analysis. The results show that Li3PO4 prepared by wet chemical reaction belongs to orthorhombic unit cell of β-Li3PO4 with space group Pmn21. Meanwhile, Li3PO4 powder prepared by solid-state reaction belongs to orthorhombic unit cell of γ-Li3PO4 with space group Pmnb and another unknown phase of Li4P2O7. The impurity of Li4P2O7 was due to phase transformation in solid state reaction during quenching of molten mixture from high temperature. Ionic conductivity of Li3PO4 prepared by solid-state reaction was ∼3.10−7 S/cm, which was higher than Li3PO4 prepared by wet chemical reaction ∼4.10−8 S/cm. This increasing ionic conductivity may due to mixed crystal structures that increased Li-ion mobility in Li3PO4.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.