Abstract
Due to the phase transition near 920°C and hygroscopicity, the growth of BaCl2 single crystals is difficult. However, owing to the suppression of the cubic–orthorhombic phase transition by La substitution and careful handling to prevent contact with the starting powders and moisture in the air, crack-free BaCl2 single crystals were grown by the micro-pulling-down technique under ambient pressure. In addition, photo- and radio-luminescence in non-activated and Eu2+-activated compounds were reported for scintillator applications.
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