Abstract
Using the top-seeded solution-growth method, Sm 1+ x Ba 2− x Cu 3O z (SmBCOss) single crystals and thick films were grown in different solvents. Inductively coupled plasma compositional analysis was performed to both Ba–Cu–O solvents and SmBCOss solid solutions. The results indicate that a nearly stoichiometric SmBa 2Cu 3O z phase with high critical transition temperature value, is controllable in a wide range of the thermodynamic parameters. The phase relation of the Sm–Ba–Cu–O system was discussed in comparison with other RE–Ba–Cu–O systems (RE=Y and Nd).
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