Crystal fractionation in the petrogenesis of an alkali monzodiorite–syenite series: the Oshurkovo plutonic sheeted complex, Transbaikalia, Russia

Abstract

The Oshurkovo Complex is a plutonic sheeted complex which represents numerous successive magmatic injections into an expanding system of subparallel and subvertical fractures. It comprises a wide range of rock types including alkali monzodiorite, monzonite, plagioclase-bearing and alkali-feldspar syenites, in the proportion of about 70% mafic rocks to 30% syenite. We suggest that the variation within the complex originated mainly by fractional crystallization of a tephrite magma. The mafic rocks are considered as plutonic equivalents of lamprophyres. They exhibit a high abundance of ternary feldspar and apatite, the latter may attain 7–8 vol.% in monzodiorite. Ternary feldspar is also abundant in the syenites. The entire rock series is characterized by high Ba and Sr concentrations in the bulk rock samples (3000–7000 ppm) and in feldspars (up to 1 wt.%). The mafic magma had amphibole at the liquidus at 1010–1030 °C based on amphibole geothermometer. Temperatures as low as this were due to high H 2O and P 2O 5 contents in the melt (up to 4–6 and ∼2 wt.%, respectively). Crystallization of the syenitic magmas began at about 850 °C (based on ternary feldspar thermometry). The series was formed at an oxygen fugacity from the NNO to HM buffer, or even higher. The evolution of the alkali monzodiorite–syenite series by fractional crystallization of a tephritic magma is established on the basis of geological, mineralogical, geochemical and Sm–Nd and Rb–Sr isotope data. The geochemical modeling suggests that fractionation of amphibole with subordinate apatite from the tephrite magma leaves about 73 wt.% of the residual monzonite melt. Further extraction of amphibole and plagioclase with minor apatite and Fe–Ti oxides could bring to formation of a syenite residuum. Rb–Sr isotopic analyses of biotite, apatite and whole-rock samples constrain the minimum age of basic intrusions at ca. 130 Ma and that of cross-cutting granite pegmatites at ca. 120 Ma. Hence the entire evolution took place in an interval of ≤10 My. Initial 87Sr/ 86Sr ratios for the mafic rocks range from 0.70511 to 0.70514, and for syenites from 0.70525 to 0.70542. Initial ε Nd (130 Ma) values for mafic rocks vary from −1.9 to −2.4, and for syenites from −2.9 to −3.5. In a ε Nd( T) vs. ( 87Sr/ 86Sr) i diagram, all rock types of the complex fall in the enriched portion of the Mantle Array, suggesting their derivation from a metasomatized mantle source. However, the small but distinguishable difference in Sr and Nd isotopic compositions between mafic rocks and syenites probably resulted from mild (10–20%) crustal contamination during differentiation. Large negative Nb anomalies are interpreted as a characteristic feature of the source region produced by Precambrian fluid metasomatism above a subduction zone rather than by crustal contamination.