Abstract
The microwave resonance absorption at wavelengths 871, 406, 305, and $118\text{ }\ensuremath{\mu}\text{m}$ (frequencies 344, 739, 984, and 2540 GHz) in tetragonal layered perovskites ${\text{HoBa}}_{2}{\text{Cu}}_{3}{\text{O}}_{x}$ $(x\ensuremath{\approx}6.0,6.3)$ in pulsed magnetic fields up to 40 T has been observed. This absorption is caused by the electronic transitions between low-lying levels of the ${\text{Ho}}^{3+}$ ion in the crystal field. The positions and intensities of the tetragonal symmetry allowed absorption lines for the crystal with $x=6.0$ in the magnetic field oriented along the principal tetragonal axes are adequately described in terms of the available crystal field parameters. To explain the symmetry forbidden absorption lines, it is necessary to take into account the effect of the inhomogeneous orthorhombic and monoclinic components of the crystal field as well as an effective exchange field from the ordered ${\text{Cu}}^{2+}$ subsystem at the ${\text{Ho}}^{3+}$ sites. The origin of the local deviations from the ideal tetragonal symmetry are ascribed to disorder in the oxygen subsystem This disorder and consequently also its impact on the absorption spectra is more pronounced in the crystal with $x=6.3$.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have