Abstract
The crystal structures of four pentakis-tert-butyl hexa-peri-hexabenzocoronenes (HBCs), each with an additional sixth substituent namely iodide, methoxy, formyl, and nitro, are presented. We show that the additional substituent has a significant impact on the packing in the solid state and the data obtained can be utilised for crystal engineering. By introducing an electron accepting substituent it was possible to achieve columnar arrangements that were previously unknown for such highly tert-butylated HBCs. In this way we provide insight into the aggregation behaviour of nanographenes with sterically highly shielded edges.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
