Abstract
Reaction of 2,6-diphenyl-3,5-di- tert-butylphenol (HOAr) with one equivalent of n-BuLi in toluene generates the hydrocarbon soluble cluster [Li 3(μ 2-OAr) 3] 1. The molecular structure of 1 consists of a six-membered ring (crystallographically imposed C 3 axis) of Li and O(aryloxide) atoms with alternating LiO distances of 1.78(a) and 1.840(7) Å.
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