Crystal and molecular structure of bis(.mu.-bromo)bis(N,N,N',N'-tetraethylethylenediamine)dicopper(I) and the kinetics of its oxidation by dioxygen in nitrobenzene

Melvyn Rowen Churchill,Jay A Fournier,John P Hutchinson,Jon A Zubieta,Mohamed A El-Sayed,Geoffrey Davies

doi:10.1021/ic00174a029

Crystal and molecular structure of bis(.mu.-bromo)bis(N,N,N',N'-tetraethylethylenediamine)dicopper(I) and the kinetics of its oxidation by dioxygen in nitrobenzene

Melvyn Rowen Churchill, Jay A Fournier + Show 4 more

https://doi.org/10.1021/ic00174a029

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Journal: Inorganic chemistry	Publication Date: Mar 1, 1984
Citations: 32

Affiliation: SUNY Buffalo State University, University at Buffalo, State University of New York, Universidad del Noreste, University at Albany, State University of New York

#Molecular Structure Of Bis #Crystal Structure + Show 1 more

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Abstract

Cristallisation dans le systeme triclinique, groupe P1 et affinement de la structure jusqu'a R=3,2%. Coordination tetraedrique deformee autour des atomes Cu. Des mesures spectrales, cryoscopiques et monometriques montrent que le produit d'oxydation est une espece dimere (TEED) 2 Cu 2 Br 2 O

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